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SUMMARY OF THE THIRD INTERNATIONAL CONFERENCE ON COLD FUSION
By: Peter L. Hagelstein,
Massachusetts Institute of Technology
Research Laboratory of Electronics
Cambridge, Massachusetts
=============================
Posted by: Jed Rothwell & Mitchell Swartz
with permission from Prof. Hagelstein.
Two Notes and Comments regarding the SUMMARY:
"Prof. Hagelstein sent me this document in "Latex" format.
I converted it to Word Perfect, and then to 80 column ASCII,
with the following conventions:
- Superscripts, including footnote numbers, are shown between curly
brackets: {4}He
- Subscripts are shown between square brackets: D[2]O
- Italics are marked by asterisks: *ab initio*
- Greek letters and symbols are spelled out: sigma, mu, Deg."
Jed Rothwell [Cold Fusion Research Advocates (404) 451-9890]
"Last month on January 16, at the MIT IAP all-day seminar on cold
fusion Prof. Hagelstein gave a fantastic detailed presentation on this
subject which left the participants in the auditorium in rapt attention.
He has graciously allowed his full work and insight of the
Third International Conference to be uploaded herefollowing to Internet.
"Incidentally, at that IAP meeting, I took a survey near the end, and
of the nearly 80+ people questioned (8 hours after starting), about 3 in
every 4 attendees read, or had otherwise received info form, the postings
on sci.physics.fusion. I submit that the proportion was a surprising
barometer for this field, and the influence of, and interest in, the net."
"Thanks are in order especially to Peter Hagelstein for this paper, but
also to Jed Rothwell (and daughter Naomi) for working it into a
format consistent with facile presentation on, and to, this net."
"This posting is made at the request of those who could not download
the 125 kilobyte file. That file has been divided into two portions
- PART I (below), and PART II (which will follow)."
Mitchell Swartz [JET Technology (617) 239-8383]
================== PART I (of II) ========================================
SUMMARY OF THE THIRD INTERNATIONAL CONFERENCE
ON COLD FUSION (ICCF3) IN NAGOYA
Peter L. Hagelstein
Massachusetts Institute of Technology
Research Laboratory of Electronics
Cambridge, Massachusetts 02139
ABSTRACT
We review highlights of the international cold fusion conference that was
held recently in Nagoya, Japan. Excess heat results in heavy water
electrolysis experiments constitute the observations with the most important
potential applications. Experiments in gas phase systems exhibit fast particle
and gamma emission that make progress toward elucidating mechanisms. The
evidence in support of a light water heat effect has improved.
INTRODUCTION
The Third International Cold Fusion Conference took place in Nagoya,
Japan between October 21 and October 25, 1992. Over 300 attendees
participated, listening to about 27 oral presentations and looking over
roughly 80 poster papers. Many people have asked me about the conference, and
rather than repeating the same things over and over again, I thought that it
would be useful to put my thoughts down on paper as a more efficient method of
communication.
Given the near complete absence of cold fusion sessions in more
traditional physics and chemistry meetings, the international conferences
represent about the only chance for people in the cold fusion field to get
together and learn about what has happened lately. The international
conferences, starting with the Salt Lake City conference in 1990, followed by
Como, Italy in 1991, and now Nagoya, Japan in 1992, have been and continue to
be the most important sources of reliable and relevant information in the
field; an important meeting was also held at BYU in 1990 which focused on
nuclear products. The field is advancing pretty rapidly these days, and since
publications tend to lag with more than a year's delay, the conferences and
conference proceedings play a key role in the field. The next international
conference was originally scheduled to take place in Hawaii in November, 1993;
I understand that it may be delayed until December.
The results presented at this conference were overall technically much
stronger than last year's conference, and benefitted by a very strong showing
from the Japanese contingent. I will first itemize what I thought were some of
the most interesting new experimental results presented at the conference.
I admit to having numerous biases. One bias is that I believe the
observations of excess power are ultimately the most important, both
scientifically and technologically. Another bias is that I favor results which
in my view help to elucidate reaction mechanisms.
Following the discussion of significant positive results, I review
abstracts and presentations of negative results. Coming from the theory end of
the field, I felt that it was appropriate for me to survey the theory papers
which were presented (in the following section); in this case, it was possible
to include a larger fraction of the papers submitted. Having my own theory as
to the origin of the effect, I warn the reader that my discussion of theory
necessarily carries a bias in favor of my world view; it is my hope that this
discussion will be useful in spite of this bias. Almost as interesting in some
cases as what was presented, was what was not presented; a discussion of work
that was absent is presented before the summary and conclusions.
For a review as long as this one, there are many issues and many details,
most of which I have made a serious attempt to get right. I would hope that I
will not make enemies of those whose work I did not include (which at this
point will include about half of all papers submitted). This review was
constructed from preprints, notes, memory, and discussions with many people in
the field -- should the reader note errors or misconceptions, I would
appreciate corrections.
SURVEY OF POSITIVE RESULTS
1. S. Pons{1,2} described briefly recent results obtained at the
Japanese-funded IMRA laboratory in Sophia Antipolis, France. During the
Como meeting (July, 1991), Pons and Fleischmann had announced that they
were able to obtain very high levels of excess power production (on the
order of 1000 Watts/cm{3}) corresponding to a factor of 10 power gain, and
that they had done so 11 times.
Part of their research since then has focused on defining a procedure
that would improve on the reproducibility of this very high power effect
(at Como, they had announced that complete reproducibility had been
attained on achieving consistent excess power at lower levels). At
Nagoya, Pons reported that this had been accomplished; that very high
levels of heat production (more than 1 kilowatt/cm{3}) were now obtained
reproducibly accompanied by a factor of 4 power gain.
The key to the new results included some advances that they outlined. One
such improvement involves the observation that the excess power
generation increases at higher temperatures. The cathode is charged at
intermediate current densities at temperatures below 50 Deg. C for
several days, and then the current is stepped up. Due to the relatively
low thermal loss of the cell and calorimeter, the cell temperature rises,
but the loading is maintained. This rise improves the excess power
generation, which in turn drives the temperature higher; the positive
feedback leads to very high excess power generation and vigorous boiling.
Pons and Fleischmann perform their calorimetry using open cell systems,
which have the advantage of being cheaper and more accessible, and allows
them to do more experiments at a time. The particular method of
calorimetry which they have developed was motivated in part by the
existence of the positive feedback described above -- Pons and
Fleischmann are able to achieve good calorimetric precision with
time-varying electrolyte levels, cell temperatures and cell voltages.
Most others have sought in their work to maintain either constant
temperature or power, or else require the presence of steady-state
conditions in their system to obtain accurate results. Very few groups
have so far taken advantage of such sophisticated methods to obtain
excess power values from their raw data; no other groups have yet
reported the ability to obtain reproducibly the high power and boiling
mode reported by Pons and Fleischmann.
It was pointed out by Pons that the calorimetry could be checked during
the very high excess power burst by measuring the time taken to boil away
the electrolyte, and using a knowledge of the heat of vaporization to
compute the total energy and hence power generation. He presented the
results of this analysis for one cell, which he said was in agreement
with the calorimetric results.
Pons stated that 2.5 moles (close to 50 cc) of D[2]O were boiled away
during a time of about 10 minutes, during which time the average *iv*
input power was 37.5 watts. The numbers can be checked, as follows: The
heat of vaporization of heavy water is about 41 kJ/mol at 100 Deg. C, and
2.5 moles of heavy water corresponds to 102.5 kJ; the energy lost during
this time in the calorimeter (primarily radiative) is 6.7 kJ. The input
electrical *iv* energy during this time is 22.5 kJ. The excess energy
produced is the output energy (102.5 + 6.7 kJ) minus the input energy
(22.5 kJ), or 86.7 kJ. The production of 86.7 kJ in 10 minutes
corresponds to an excess power of 144.5 watts, and a power gain of 3.85.
The volume of the cathode was given to be 0.0785 cm{3}, which was noted by
many (this volume was in error, as will be commented on shortly). The
average excess power claimed during the boiling episode was 144.5 Watts,
which would correspond to 1841 W/cm{3}.
The cathode geometry was given by Pons to be cylindrical, with a diameter
of 2 mm and a length of 1.25 cm. I note that this geometry does not
correspond to the volume quoted by Pons above -- a rod of these
dimensions would have a volume of 0.03927 cm{3}, which is almost precisely
a factor of 2 smaller than the volume given during Pons talk. Pons has
confirmed that this smaller volume is correct (the correct value appears
in their conference proceeding{2}). I will continue my discussion here
using the corrected power per unit volume, which is 3682 W/cm{3}.
The anomalous excess energy production in this experiment is
considerable, as can be calculated. In 1 minute, 8.7 kJ of excess energy
is produced. At a density of 12.02 g/cm{3} and an average mass of 106.42
amu, pure Pd contains 6.8 X 10{22} atoms/cm{3}. The total number of atoms
in the cathode is 2.7 X 10{21}, or 0.0044 moles. In 1 minute, the excess
energy production is 1.96 MJ/mole, which corresponds to 20.3 eV/atom of
Pd. This number is greater than can be accounted for by a chemical
explanation for the effect. After 10 minutes, the cathode has produced
203 eV/atom.
In the absence of current flow, film-boiling limits the heat flow from
the cathode at cathode temperatures higher than about 120 Deg. C; the
maximum heat flux from the rod under these conditions is limited to I
think somewhere near 125 Watts/cm{2}. The surface area of the cathode,
including the top and bottom, is 0.85 cm{2}, which leads to an observed
average heat flux of about 170 Watts/cm{2}. This number is comparable to,
but greater than my version of the film-boiling limit given above, and
was a potential cause for concern.
Pons and Fleischmann have considered this effect, and have found
experimentally that the presence of current flow delays the onset of
film-boiling to higher temperatures and higher heat fluxes. In their
conference proceeding, they claim{2} to have observed heat transfer rates
during electrolysis in separate experiments which are between 1-10
kW/cm{2}. I consider this result to be very important.
The cathode gets very hot in these experiments. Pons and Fleischmann have
observed the Kel-F supports at the base of the cathodes to melt, from
which the presence of temperatures in excess of 300 Deg. C are inferred.
A direct measurement of the cathode temperature is currently problematic;
Pons is currently interested in practical proposals as to how to do this
without impacting the electrochemistry.
A common misunderstanding often occurs in the discussion of the results
of Pons-Fleischmann experiments which is of interest here. It is
sometimes argued that the energy production during a short event can be
disregarded, since there may exist energy storage mechanisms which could
have been collecting energy at a low level for a long period of time. For
example, the total energy output from this experiment would not be very
much larger than the total input energy if no heat excess had occurred
prior to the boiling event (1 watt-day = 86.4 kJ). This type of argument
seeks to make palatable the notion that since the total energy excess
measured over days is small compared to the input (and hence there might
exist a signal to noise problem in the measurement), the measurement can
be dismissed. As discussed above, this type of argument completely misses
a key implication of the experiment -- specifically, that there exists no
known physical mechanism which could store the energy observed to be
released during the boiling episode.
It is true of this experiment as well as of others to be described below,
that no products or "ashes" of the heat have been found and verified that
are commensurate with the energy production. This will be discussed
further below.
2. M. McKubre{3,4} described experiments done at SRI during the past several
years. They have developed closed cell flow calorimeters, which are
ideally *first principle* calorimeters (which means that the heat flow
out of the cell goes into the flowing water coolant, and the power
generation is determined by measuring the mass flow rate and output to
input flow temperature difference, with no calibration required). They
have succeeded in reducing the conduction losses (which are not first
principle contributions) down to the order of one per cent, and then they
calibrate the Fick's law constant associated with the conduction losses.
Overall, the SRI calorimeters achieve a relative accuracy in the
calorimetric measurements which is on the order of a few tenths of a per
cent.
The SRI group reported the development of a procedure at Como that
appeared to yield excess heat essentially every time, and this method is
described in the Como conference proceedings. Highlights of these
experiments were discussed. A significant advance that was pioneered by
the SRI group was described: it consisted of the addition of aluminate or
silicate to the electrolyte, which caused the formation of a colloidal
surface layer that passed light ions (deuterium, lithium, boron,...) and
shielded the surface from impurities; this procedure improves the ability
of the Pd rod to maintain a high loading ratio.
Two distinct modes of excess power generation were observed; one in which
the excess power occurs at relatively low levels (1%-50%) and responds to
changes in current density (they have observed 38 occurrences of this
mode, lasting hours to many days), and one that is characterized by much
higher relative power levels (up to 350% excess) and appears to be
insensitive to changes in current (this mode has been observed 3 times,
lasting many hours).
For the first mode of heat generation, SRI finds that the excess power
rises linearly with current above a threshold current density (which is
on the order of 100-200 mA/cm{2}). A graph illustrating this appears in
their conference proceeding.{4} This is in apparent contrast with the Pons
and Fleischmann results, which showed a possible quadratic component to
the increase above threshold current. Discussion during the meeting
pointed to the fact that the SRI experiments are run at constant
temperature, while the temperature of the Pons and Fleischmann cells
increase when excess heat is produced.
Mckubre presented a graph of excess power production as a function of
fractional deuterium loading as determined from resistance ratio
measurements. This dependence was found to increase roughly parabolically
above a loading of 0.85 (*P[xs]*~(x-0.85){2}) up to loadings near 0.95,
which is as high as had been achieved during their C1 experiment.
The group has spent considerable effort chasing down and quantifying
uncertainties in the SRI experiments, and are now able to assign
meaningful error bars to essentially all quantities measured and inferred
in their experiments. The result of this analysis yields rather high
sigma numbers on the excess power measurements (in excess of 50 sigma on
some of the best data analyzed so far).
Their largest power numbers correspond to on the order of 15 W/cm{3}; it
would take a small number of hours of running at this level to defeat a
chemical storage explanation. Their highest excess total energy numbers
have reached 200 MJ/mole of Pd, which corresponds roughly to 2 KeV per Pd
atom; this level of excess energy production cannot be of chemical
origin.
3. K. Kunimatsu{5,6} of IMRA JAPAN Co. in Sapporo presented results on their
heavy water electrolysis experiments. A number of things struck me as
being interesting about this talk, aside from the fact that this is one
of the first presentations of anything from this group at a conference at
which I have managed to be. This effort appears to have a great deal of
resources and some nontrivial technical expertise. They reported excess
power measurements as a function of loading (where the loading was
determined through measurements of the deuterium gas pressure in the
cell), and arrived at essentially the same dependence of excess power on
loading fraction as SRI, but with the cut-off shifted down by a few
points relative to the SRI results (from a D/Pd ratio of 0.85 inferred
from a resistance ratio measurement, down closer to 0.83 determined from
measurements of the D[2] gas pressure{6}). The peak excess power occurs
when the current density is greater than 100 mA/cm{2}, and the peak excess
power which appears on the graph in Ref. 6 is about 35%.
The IMRA experiments differed qualitatively from the SRI and
Pons-Fleischmann experiments in that they were run in fuel-cell mode.
Conventional Pons-Fleischmann electrolysis experiments are run such that
D[2] gas is generated at the cathode and O[2] gas is generated at the
anode. IMRA has developed a pressurized cell in which deuterium reactions
occur at the anode. Cells operating in fuel-cell mode have been developed
in the past, however, this is the first time that I am aware that a
Pons-Fleischmann cell has generated excess power sufficiently reliably
while operating in such a mode to produce relatively high quality excess
power data of the sort presented.
This group seems to have good people, good funding, and much expertise.
They presented several poster papers on studies of excess power
generation, and the absorption of hydrogen and deuterium in palladium
cathodes{7-10} I think that we will be hearing much more from them in the
future.
I note that a positive correlation between loading and excess heat
production in a Pd/D modified Pons-Fleischmann experiment was reported by
Scaramuzzi and De Ninno in a poster paper.{11,12}
4. Ya. R. Kucherov{13-15} from the Luch Association, Podolsk, Moscow Region
described experiments that I thought were very important.
The experiment involves using a glow discharge to load a Pd (or other
metal) foil (1 cm X 1 cm X 0.1 mm - 1.0 mm) in D[2] gas at 10 torr, with a
400 V discharge (10 - 500 mA current). Apparently this group has had
considerable experience with glow discharges and is aware of several
tricks that help to preserve the surface of the cathode which helps to
attain very high loading (a D/Pd ratio of more than 1).
Numerous effects are observed; excess heat production will first be
considered. Temperatures were monitored using W-Re thermocouples in the
cathode and anode, and also CC thermocouples in a heat collector some
distance from the cathode. Calibration was done through comparing
temperature histories of "live" Pd cathodes (cathodes producing neutron,
gamma and fast particle emission) in deuterium with those of "worn out"
cathodes (cathodes producing no anomalous emission). Excess power
production at the level of tens of watts is observed; their best result
out of 78 experiments is a 33 watt excess representing a power gain of a
factor of 5. Given the small total cathode volume, the resulting power
generation rate is quite high; the highest values are on the order of
3000 watts/cm{3} of Pd. The highest total energy production observed to
date exceeds 20 kJ.
After about 100 seconds after the start of the discharge, neutron
emission is observed (a huge signal, reaching up to 10{6} neutrons/sec in
some experiments). The neutron detection described in their earlier work
was done using RUP-1 silver activated ZnS scintillation detectors and
type SNM-18 gas discharge ({3}He) detectors. The 10{6} neutron/sec signal
appeared in the scintillation detector as 2000 counts/sec at a distance
of 1 meter; the signal showed up as 10000 pulses/second at a distance of
30 cm on the SNM-18 detector. No emission was observed using a hydrogen
discharge.
After a while, gamma emission is then observed (also a huge signal, up to
10{5} gammas/sec in some experiments). The gamma emission was studied
using four detectors (Ge-Li, stilbene, NaI and SPS plastic); most of the
recent results were obtained using a liquid nitrogen-cooled Ge-Li DGDK-50
detector with 1.6 keV resolution at 1332 keV, and an efficiency of 10{-3}
at 511 keV. An example of an anomalous gamma spectrum from Pd is shown in
a recent publication{16}.
Gamma lines were identified from short-lived isotopes (the gamma spectrum
returns to its initial state in 3-5 days), and some of the identified
lines originate in isotopes in the neighborhood of Pd (lines originating
from isotopes with a nuclear charge of *Z*-3 to *Z*+8, where *Z*=46 for
Pd, were observed).
A very substantial flux (10{4} to 10{6} ions/sec) of fast ions is emitted
from the cathode, and silicon surface barrier detectors were used for
detection. The bulk of the emission occurs between 1-5 MeV, and in some
experiments lasts for a few minutes after the discharge is switched off
which allows for an accurate determination of the spectrum. Correlated
fast ion emission was registered on calibrated CR-39 plates installed
inside the discharge chamber.
A small fraction of the fast ions are observed at high energy; peaks were
observed at 6 MeV, 12 MeV and 16 MeV. The mass of the particles at 12 MeV
and higher was determined to be greater than or equal to 4, as determined
through measurements with different barrier thicknesses.
5. There was a Chinese team{17-20} that presented results from a somewhat
similar system to that described by Kucherov. A glow discharge was
created by applying high voltage (7-11 KV, 50 Hz) between two electrodes
inside of a glass bulb containing deuterium at low pressure (4-13 torr).
A thin (1 micron) metallic layer of the electrode material (for example,
Pd) was deposited on the interior of the glass bulb. The glow discharge
current was less than 100 mA; an anomalous current was observed with an
average value of 1 A, and excursions up to 10 A. A D/Pd ratio of 0.5-0.8
was claimed to have been obtained.
Substantial neutron emission (13-330 neutrons/sec) was observed, and the
energy spectrum was resolved with a recoil proton fast neutron
scintillation spectrometer. The resulting neutron spectrum contained both
2.0-2.5 MeV neutrons, and broad emission between 2.5-7.0 MeV; most of the
emission occurred above 2.5 MeV.
Neutron emission was also recorded from metals chosen at random, and the
signal strength varied with metal according to the order Pt, Nb, W, Pd,
Ag, Cu, Mo and Fe. The fluence observed from the D/Pt system was 1.2 X
10{4} neutrons/sec.
The energy spectrum of the neutron emission for these metals was also
observed. In the case of the D/Pt emission shows broad emission up to
about 8 MeV, decreasing generally with increasing neutron energy, and
with a number of possible peaks appearing.
Intense gamma spectra were also observed with a NaI scintillation counter
during the experiments; the gamma ray yield was about ten times that of
the neutron yield. The gamma spectrum of D/Nb showed lines at tens of
KeV, 3.4 MeV and 5.8 MeV, and some unresolved emission below 7 MeV.
These experiments seem to me to be similar to the experiment described in
1989 by Wada.{21} Another experiment of this sort was reported by Tazima,
Isii and Ikegami, and also by Jin, Zhang, Yao and Wu, at the Como
conference.
6. E. Yamaguchi of NTT presented a paper{22,23} on {4}He production from a PdD
foil that is sandwiched by gold and MnO[x]. I think of the NTT research
labs as being the ATT Bell Labs of Japan, which has an excellent
technical reputation. This paper attracted considerable interest in the
Japanese media, and there were reports that the price of the NTT stock
climbed as a result. The NTT stock climbed a bit more than 10%; Morrison
pointed out in his review that the stock went back down to its
pre-announcement value within a few days.
In the experiments that he reported, a current of 0.5-0.8 A/cm{2} is
applied perpendicularly to the sandwich. The foil produces heat at a
level of 0.5-5 Watts for about 1000 seconds (this is the case whether the
foil is PdD or PdH), and then explosively outgasses. At the peak of the
outgassing, the samples undergo substantial plastic deformation which
lasts for about 10 seconds. During his presentation, it was not obvious
whether the temperature rise observed was being claimed as anomalous or
not. If the foil is deuterated, these phenomena are accompanied by {4}He
emission.
Yamaguchi previously reported at the BYU conference very high levels of
neutron emission from this system at a 10{6} neutrons/second. The
experiments described at Nagoya included only helium, heat, and fast
charged particle detection.
The {4}He emission is monitored using an expensive high resolution mass
spectrometer that is capable of distinguishing between {4}He and D[2]
signals, as was demonstrated. A minor peak in the data appears near the
expected HT mass position, and Yamaguchi claimed that this signal
indicated the presence of HT (Claytor notes in his trip report that the
HT signal, if real, would imply a "radiological hazard (> 10 Ci)."). The
H[2]D trimer is more massive than D[2] and does not interfere with the
{4}He measurement.
Yamaguchi sees {4}He in his mass spectrometer when he uses PdD, and he
sees no {4}He when he uses PdH. Yamaguchi stated that the amount of {4}He
was "consistent with the heat," but if he gave figures for the amount of
{4}He produced, I missed them. Given that heat occurs for PdH runs as well
as for PdD runs, it is not clear what the statement means. Hopefully this
issue will be clarified at a later date.
When asked whether the {4}He is due to contamination, Yamaguchi argued
that it is not in the D[2] gas used, it is not in the metal, and the
vacuum system being used is a high quality system of the type used in
semiconductor research that will hold a 10{-6} torr vacuum for a month
without pumping.
Yamaguchi also sees 3 MeV protons and fast alphas at 4.5-6 MeV using two
identical systems based on silicon detectors (Canberra
Si-SSD:PD-450-19-700-AM; active area=4.5 cm{2}, active thickness = 700
mu). Protons were observed at 3 MeV, and were attributed to the *p+t*
branch of the *dd*-fusion process. Significant emission was observed
between 4.5-6.0 MeV; by comparing signals with and without an intervening
7 mu foil, these signals were identified as being due to either alphas or
{3}He nuclei. The total number of fast particles detected was a few
hundred per experiment.
The experiment which Yamaguchi and Nishioka have constructed looks very
impressive; I got the impression that the helium measurement capability
was relatively new. I think that the {4}He signals are real, but I am less
convinced yet that it has been made through an anomalous effect. The
strongest argument in support of it being genuine is the rather strong
time-correlation of the {4}He signal with the temperature excursion of the
foil.
The NTT group has been active for years, and by now I think that the
basic anomalies which they observe are likely to be right. The new result
presented at Nagoya is the helium measurement, which I will be more
comfortable with after Yamaguchi and Nishioka have had more experience
exploring. I look forward to more results from this group.
I note that the first significant claim for substantial {4}He production
in Pons-Fleischmann electrolysis experiments were made at Como by Miles
and coworkers at China Lake. Previous negative results had been obtained
in searches for helium in the cathode; Miles and coworkers claimed the
observation of {4}He in the gas stream. Miles presented a paper at
Nagoya{24} which gave an update of the group's recent efforts, which have
been hindered by an inability to obtain significant excess heat.
Bockris reported at Nagoya{25} observations of {4}He above background (by
factors of 2-100) that accompanied tritium production (described below);
the helium was analyzed by thermal expulsion and mass spectroscopy.
7. S. Isagawa et al from the Japanese National Laboratory for High Energy
Physics (the KEK collaboration) reported their results on experiments
involving searches for heat, tritium and neutrons in Pons-Fleischmann
cells.{26,27} I was impressed that the KEK was working at all in this area,
and even though they have apparently had an effort at some level since
1989, it appeared to me from their presentation that they have more or
less just gotten started.
Most of their results to date are negative, and it appears that they are
confident that they are going to get the expected (that is, null)
results. Of the possible excess heat events that they have observed so
far, they have been able to rule out all but one as being due to known
(non-anomalous) causes. Neutron emission is mostly not observed, but they
have one event at 3.5 sigma of excess neutron emission (23 q 7
neutrons/sec) recorded over nine hours from one PdD cell after 20 hours
of electrolysis.
Although their results to date have little impact on the field, should
they continue, their contributions could be and should be substantial in
time. One thing that this group would be able to do which few other
groups in the field are as well suited to do to bring on board the
physics community. Positive results obtained at the KEK would stir
interest in other physics laboratories as almost no other result. The
physicists have written off Pons and Fleischmann, so they are free to
ignore the claim of kilowatt/cm{3} reported at the conference; but if the
KEK gets 10% heat power at 10 Watts/cm{3}, I would bet that every physics
lab on the planet will likely be pulling out their electrochemistry sets
again.
8. T. P. Perng of National Tsing Hua University in Hsinchu, Taiwan described
observations of excess power from molten salt electrolysis experiments as
part of a paper on heavy water Pons-Fleischmann experiments.{28} Although
I did not recall seeing it, and I have no notes of it, numerous friends
at the conference mentioned it to me (including Liaw). I also received a
preprint of this work.
Liaw and coworkers at the U. of Hawaii described at the last two
international cold fusion conferences experiments using molten salt
electrolysis with Pd and Ti anodes in a LiCl-KCl eutectic saturated with
LiD. At Como, the group reported the observation of excess power at a
level of about 10 times the input electrochemical power in Pd (up to a
30% increase over electrochemical plus heater power), with an energy gain
reported as about 1 GJ/mole Pd or 6 MJ/mole D[2]. The Pd anode volume was
0.040 cm{3}, so that the excess power per unit anode volume is about 250
watts/cm{3}.
This result was important because the power excess was so large relative
to the electrochemical input power, and because the temperature excess
was on the order of a hundred degrees centigrade, which would have the
potential for efficient energy extraction.
Little progress has so far been reported toward a reproduction of the
Liaw experiment. Perng described results from an experiment performed to
provide a confirmation of the Liaw experiment; the power excess claimed
was on the order of 2-5 times the input power.
The preprint{29} from C. M. Wan et al consists of an abstract and copies
of 11 figures, from which I will attempt to give an account of the work.
Following Liaw, the palladium electrode is used as an anode (instead of a
cathode as is done in conventional Pons-Fleischmann experiments),
immersed in a KCl-LiCl eutectic saturated with LiD. The anode dimensions
are 6 mm diameter and 5 cm length. The molten salt sits in an aluminum
container which serves as the cathode. The temperature is sensed using a
thermocouple embedded in a quartz tube which is placed in the molten salt
in the general vicinity of the Pd anode. A Ni-Cr alloy resistive wire
heater (encased in quartz) is wrapped around the cell, within a ceramic
fiber insulator. Nearby is a {3}He neutron detector with a 0.01% detection
efficiency.
From the figures and the abstract, it is clear that a time-dependent
excess neutron signal appears following 200 hours of electrolysis, at
twice background (background is 5.51 q 0.44 cpm) corresponding to 800
neutrons/sec. This neutron signal is rather clearly correlated with the
excess power production which is time-dependent and rises to about 10
watts. Given the large anode volume, this level of excess power
corresponds to about 7 watts/cm{3}. The associated temperature excursions
are about 25 Deg. C, with one excursion up to 50 Deg. C.
The abstract quotes power gains of 5 to 108 for the 6 mm Pd rod which is
5 cm long, and power gains of 8 to 560 from a 4.5 mm diameter rod. These
numbers are very high and represent excesses in comparison with
electrochemical power rather than total input power; I think that the
highest numbers correspond to modest excess powers observed at low input
current level.
There was an abstract from the National Tsing Hua University by Yuan et
al that described a molten salt experiment;{30} I do not know whether this
paper was presented. I suspect that this paper may not have been
presented, and that Perng was reviewing results obtained by his
colleagues.
9. There were several papers on attempts at replicating the Takahashi
experiment that captured the attention of the Japanese press earlier this
year. A. Takahashi described earlier this year obtaining tremendous
excess heat in a heavy water electrolysis experiment that ran at an
average of 1.7 output power over input power for about two months.{31,32}
The total excess enthalpy generated was claimed to be about 2250 MJ/mole
Pd (more than 20 KeV per Pd atom), which is one of the highest claims to
date from this type of experiment. Following Takahashi's announcement,
many laboratories attempted a replication.
Takahashi's experiment is similar in many ways to the classical
Pons-Fleischmann experiments with some variations. A Pd foil from Tanaka
Kikinziku Kyogo (Tanaka Precious Metals Co.) with dimensions 2.5 cm X 2.5
cm X 1 mm is used for a cathode instead of a rod. The electrolyte volume
is very large (700 cc of D[2]O with 0.3 M LiOD). An innovation of
Takahashi is the use of a time-varying current which alternates between a
high mode (4-5 amps) and a low mode (0.2-0.4 amps) every six hours.
Takahasi's calorimeter is an open cell flow calorimeter, where water from
a chiller is flowed through a coil inside the cell, and the power is
determined from a knowledge of the mass flow rate and the input-output
temperature difference. An advantage of this type of calorimeter design
is that it is able to function at near constant temperature when high
power is applied to the electrochemistry. The temperature was monitored
using teflon coated thermocouples at the inlet, outlet, and cell
interior. The cell was calibrated before and after the run in the initial
experiment, and the calibration lines were approximately reproduced.
The total input energy for the initial experiment was 250 MJ, the total
output energy measured was 410 MJ, leading to an excess of 160 MJ.
Takahashi's excess power level claimed was 32 watts averaged over two
months, with excursions to 100-130 watts. The cathode volume is 0.625
cm{3} (0.0706 moles), so that the average power density is 51 watts/cm{3}
and peak excursions are 160-208 watts/cm{3}. As discussed above, a
chemical explanation of the effect (barring other systematic errors) is
defeated in less than half an hour at the high excess power levels.
Attempts at replication had varying degrees of success, but no one has
been able to reproduce the very high power levels claimed by Takahashi.
In the reproduction which Takahashi reported at Nagoya, the excess
average power was 8 watts, with excursions to 15 watts.
Takahashi's method comes with the recommendation that it is a potentially
technically easier experiment than other experiments which have been
reported. It is less exacting in the rigorous electrochemical purities
required as compared to the SRI experiments; the cathodes from Tanaka
metals are readily available to workers in the field, in contrast to the
Johnson-Matthey cathodes employed by Pons and Fleischmann. The system is
in principle relatively cheap to set up; Mallove{33} described a version
of the Takahashi experiment which was built up using about $10K of
hardware funds.
Storms at LANL is claiming excess heat from a Tanaka batch 1 foil, and no
heat from a batch 2 foil.{34} The anomalous power from the first foil was
more than 20%. The batch 2 foil suffered an increase in internal volume
on loading, which Storms suggested might be used as an indicator of
whether a cathode was suitable for heat experiments. No one has reported
a success with a batch 2 foil that I am aware -- batch 3 appears to be
free of this problem.
Celani{35,36} described efforts to reproduce the Takahashi experiment at
his laboratory in Frascati. Experiments were run in an open cell flow
calorimeter using two Tanaka metals batch 1 cathodes, one Tanaka batch 2
cathode, and one IMRA batch 1 cathode. Positive results were obtained
with the Tanaka batch 1 rods (at 8% and 25% peak power excess) and with
the IMRA rod (12% peak excess). No excess power was observed with the
Tanaka batch 2 cathode. Blank experiments were performed where a gold
cathode sheet was substituted for the Pd cathodes, and no excess was
observed. A correlation between high loading and excess heat was noted;
small amounts of excess tritium were reported for the runs which gave
excess heat.
Oyama{37} reported a 2.4% excess energy, which is small, but was measured
with much smaller error bars; a light water blank showed no excess.
10. Tritium production was discussed by several groups. The existence of such
an effect is interesting because it constitutes an additional signature
of the presence of a nuclear phenomenon; tritium cannot be made
chemically. An additional feature of many tritium experiments is that the
tritium is not accompanied by neutron emission (neutron/tritium ratios of
10{-7} - 10{-9} have been reported). The *dd*-fusion reactions would
produce neutrons and tritons in roughly equal amounts, so that the
observations imply either a new mechanism or else a very significant
modification of the fusion reactions. Possibly more significant is that
14 MeV neutrons from *d-t* fusion reactions would be expected from
secondary reactions if the tritium nuclei were created with MeV-level
kinetic energy. The very low neutron to tritium ratios claimed imply a
very low triton energy (below 10-15 keV), sufficiently low to be
inconsistent with all but the most exotic reaction mechanisms.
At Como, strong presentations of tritium production were made by Will,
Claytor, Lanza, Szpak. Will has not been active in the field during the
past year, and did not attend the Nagoya conference; Lanza has continued,
but was not able to attend this year; Szpak has continued, but was also
not present at Nagoya.
Claytor{38} (whose work impresses me) described further experiments on
tritium production in which a stack of alternating layers of palladium
and silicon is placed in deuterium gas at over 10 atmospheres, and a
pulsed current is passed through the stack. Reproducible tritium
production is claimed at levels of 0.02-0.2 nCi/hr (1.1 X 10{6} - 1.1 X
10{7} tritium atoms/second). Advances which the LANL group has made during
the past year includes: reduction of background tritium, improvement in
detection sensitivity, improvement in reproducibility at higher tritium
generation rates, and the innovation of working with stacks using Pd
built up from powder. Upper limits on neutron emission can be placed from
their work as reported at Como of 4 X 10{-9} neutrons/second; the {3}He
neutron detector which they have used (which I saw during a recent visit
there) has a roughly similar efficiency for 14 MeV neutrons as for 2.45
MeV neutrons (the detector is more sensitive at 2.45 by a factor of 1.5
according to Menlove).
Bockris{25} described two tritium experiments at Nagoya. In one
experiment, a reproduction of the Szpak-Boss experiment described at Como
was attempted. Szpak codeposited Pd on either a Cu or Ni substrate from
PdCl[2] in D[2]O containing 0.3 N LiCl; continued electrolysis resulted in
tritium production. The Pd was observed to plate out during the first 6-8
hours, and excess tritium would be detected about 10 hours later. The
experiment Bockris reported involved codeposition of Pd on gold, and
tritium production was observed to start as soon as 10 hours after the Pd
deposition, and production up to 3 times background was observed. This is
the first successful confirmation of the Szpak experiment of which I am
aware. Bockris did not obtain the high degree of reproducibility claimed
by Szpak.
I note that Miles also described{24} attempts to reproduce the Szpak
experiment, and reported the observation of a modest tritium increase,
but "not clearly beyond levels expected for electrolytic enrichment due
to isotopic separation factors."
Much more spectacular are the results reported by Bockris of Chien's
experiments on tritium production in a Pd electrolysis experiment where
massive amounts of tritium (more than 10{15} atoms) were observed. This
report is very significant because it represents a new claim for very
high levels of excess tritium.
Early on, reports of very high levels of tritium were reported to have
been observed at Texas A&M, corresponding to production rates on the
order of 10{10} tritium atoms/cm{3} or higher. These experiments were
clouded by charges of fraud (this charge was apparently investigated by a
panel hired by Texas A&M, and not substantiated), and by the observation
of high levels of tritium contamination in Pd claimed by Wolf (found by
dissolving Pd rods in acid, and then performing scintillation counting on
a neutralized version of the resulting solution). Similar experiments
reported by Cedzynska (differing in that the distillate of the solution
was analyzed by scintillation counting) failed to show contamination at
the high levels reported by Wolf, and in addition found that false
positives could occur when the solution was not first distilled.
Subsequently, much more stringent controls were done to attempt to defeat
the insidious tritium contamination claimed by Wolf, and new post-Wolf
experiments were reported in which anomalous tritium production has been
claimed. Except for experiments reported by BARC, most new claims have
involved tritium production rates many orders of magnitude below those of
the initial claims (the new claims generally ranged from 10{4} - 10{6}
tritium atoms/second). The significance of the Chien experiments is that
the tritium production rate claimed by Chien (in a post-Wolf experiment)
are some of the first to approach the very high early (pre-Wolf)
experimental claims. Much care was taken to avoid possible contamination:
samples from the same rod were dissolved in aqua-regia, and the resulting
solution distilled, and then analyzed using a scintillation cocktail
following the method described by Cedzynska at Como.
Chien's earlier experiment was carried out at the Institute of Nuclear
Energy Research in Lung-Tan, Taiwan. The palladium cathodes used were 1.0
cm in diameter, and 1-2 cm long; Pt wire wrapped around at a distance of
4 mm was used for the anode. Electrolysis was carried out in heavy water
with 0.1 M LiOD; tritium assay was done with a scintillation cocktail.
Solutions exhibiting high tritium activity were sampled at the time of
the experiment (10/89), and then resampled 10 months later (8/90) in
order to observe the tritium decay from the sample. Tritium generation
rates of 10{6}-10{9} atoms/second were determined, lasting for a total of
20-30 days. The numbers claimed by Bockris at Nagoya{25} for the Texas A&M
version of the experiment correspond to about 10{7} atoms/sec/cm{2} of
surface area, in experiments with a 3-6 cm{2} surface area.
11. V. A. Romodanov gave an oral presentation in the theory panel at
Nagoya.{39} Romodanov's command of the English language was imperfect; he
read from his paper for more than 20 minutes in a thick Russian accent.
Essentially no one with whom I talked understood the point of what he
said, and his abstract did not particularly add to the information
content. Given that his talk occurred in the theory section, and given
that his theory appeared to be largely classical fusion modified somewhat
by lattice effects, no one was expecting that a major experimental result
was buried in his presentation. Two things about his talk raised flags
for me, indicating that I should try to follow up if possible. One was
that he was from Luch, which is the same place Kucherov is from...and I
was very impressed by Kucherov's results. The second thing that I recall
was that there was a table giving some very high tritium numbers; at the
time I thought they were theoretical estimates because they were so
large.
Romodanov handed me a preprint{40} which explained in rather clearer
English what was the content of his talk. I will focus on what I consider
to be the single most important part of his presentation, which if true,
is of fundamental importance. Romodanov described the results of glow
discharge experiments which appear to have been done on a system very
similar to that discussed by Kucherov (see above in this review).
Romodanov and his colleagues focused on the detection of tritium produced
in glow discharge experiments in Pd and in other metals.
The glow discharge was run in deuterium gas at 100-200 torr, with an
applied voltage in the range of 40-125 V, and a current of 3-4 A (a wide
range of operating conditions are described in the paper, and the numbers
I have chosen appear on one table -- I am not completely certain from the
paper that the tritium generation was done with these parameters).
Various cathode metals were used, including Y, Mo, Nb, Er, Ta, and W; as
disks with a diameter of 13 cm and a thickness between 500 mu and 1 mm,
or rods of 0.5-2 cm diameter. The cathode temperatures were measured to
be between 970 Deg. K and 1670 Deg. K, with only minor (15% or less due
to anomalous self-heating effects).
Tritium generation rates between 10{5} atoms/second and 10{9} atoms/second
were measured in the different metals under various conditions. The
largest rate (1.7 X 10{9}) was obtained in Nb at 1170 Deg. K,
corresponding to an increase in tritium activity in the deuterium gas of
2.3 X 10{4}. The neutron emission was measured in these experiments with a
"radiac instrument RUP-1," which appears to be a scintillator with silver
activated ZnS dispersed in transparent plastic (sounds similar to the
detector used by Kucherov), and a neutron to tritium ratio of 1.8 X 10{-7}
was obtained.
12. R. Notoya from Hokkaido University brought a light water demo that was
set up and operated in the hallway of the conference{41}. The demo
consisted of two cells: in one cell was a resistive heater, and in the
other cell was a nickel cathode immersed in a light water K[2]CO[3]
electrolyte, similar to the method of R. Mills and colleagues.{42}
Notoya's method differs from Mill's method in that (1) the Notoya cathode
is made of porous nickel, and the Mills cathode is plain nickel; and (2)
Mills uses an intermittent current, while Notoya uses a constant current.
The resistive heater was driven at 2.1 Watts electrical *iv* input; the
electrolysis cell was driven so that the joule heating in the cell was
also 2.1 Watts. The *iv* input into the electrolysis cell is actually
higher by about 30%, but since electrolysis is occurring with a Faradaic
efficiency near unity, the power ending up inside the cell is matched as
long as no recombination occurs in the space above the electrolyte. The
live cell ran higher by about 15 Deg. centigrade than the blank, as could
be inspected visually by observing alcohol thermometers immersed in both
cells. Notoya claims that the light water cell temperature implies a
factor of about 3 more net power input, or roughly 6 watts of heating
present.
This was interesting for a number of reasons. This was the first live
demonstration of excess heat production at a cold fusion conference that
I am aware of. I have always thought that live demos would start to show
up at conferences and at presentations, but I had figured that the first
ones would be heavy water demos. I thought that it was significant that
Notoya's system works well enough for her to be willing to bring it as a
demo at a major international conference.
Many of the "established" workers in the field who have put in
substantial effort on heavy water Pons-Fleischmann cells and have
observed heat simply do not believe that a heat effect can be observed in
light water. Among other arguments that can be heard is that if the
effect is either nuclear or is fusion, it must involve deuterium. Others
in the field argue that the light water claims are simply due to sloppy
experimental work. Independent of the correctness of the various
assertions, it is almost humorous to find senior members of the cold
fusion community sounding very much like their critics and tormentors of
1989.
The first reports of heat from light water experiments were actually from
Pons and Fleischmann early on in 1989; when I last spoke with Fleischmann
about light water experiments about a year ago, he was firm in his
conviction that it was not possible to get excess heat from a light water
cell.
R. Mills, who is the originator of this particular Ni/K[2]CO[3]
experiment, has no previous reputation or standing as an electrochemist,
calorimetrist or physicist. He rejects the notion of cold fusion as due
to nuclear effects completely (in fact, he does not wish to associate
himself with the cold fusion community, and does not consider his effect
to be related in any way to cold fusion), and has developed his own
theory as to why his experiment works; his theory is based on the
proposed existence of orbitals of hydrogen that lie below the 1*s* level.
An explicit assumption in the Mills and Farrell theory is that the
electronic charge distribution in hydrogenic states consist of charged
shells of infinitesimal thickness. In order for this proposal to be
correct, quantum mechanics must be incorrect (which Mills believes -- he
offers his theory as a replacement for quantum mechanics). There have
been no observations of such states, and the existence of such states
would likely not be consistent with the observed stability of atoms as
atoms.
Reproductions of the Mills experiment have been reported previously.
Noninski{43} published positive results from his experiments; Noninski
views his experiment as a verification of the work of Fleischmann and
Pons, who state explicitly (in a 1989 patent application) the possibility
of excess heat in a light water cell with Ni as a cathode material. Mills
was apparently unaware of Fleischmann and Pons patent application and its
relevance.
Confirmations of the Mills light water experiment have also been reported
by Srinivasan,{44,45} and Bush and Eagleton.{46} Notoya and her laboratory
come with good reputations; her confirmation of the Mills experiment
(complete with demo) is probably the most significant endorsement of the
light water excess heat results standing.
Notoya's demo is an open cell system. It operates at a sufficiently high
excess power that recombination or other effects that would make an open
cell system perform differently from a closed cell would not change the
essential result even if the recombination and other secondary effects
were taken into account incorrectly or ignored. You can put your finger
on the tubes Notoya's demo to convince yourself that a very significant
temperature difference occurs. This was also claimed for the Mills
experiment, as well as for other experiments reproducing the Mills
result.
During the conference and afterwards, a virtual firestorm of controversy
arose concerning the difference in wires that were attached to the live
cell and to the blank. A student of Steve Jones suggested that since
smaller diameter wires were used on the blank, that the reduced voltage
drop across the resister could account for the difference. After the
conference, Notoya replaced the offending wires, and reported essentially
no difference in the resulting blank temperature.
Notoya's demo was brought to the US and set up at MIT during the first
week of December. During the day and a half before her presentation at
MIT, the live cell and resistive blank ran at very nearly identical
temperatures, consistent with no excess power production. Notoya
attributed this to contamination of the nickel cathodes. After her visit,
she returned to Japan and set up her demo in a laboratory in Tokyo where
excess heat was observed. A few days later, she was back at MIT,
attempting for a second time to demonstrate excess power production.
During this visit, a temperature excess was seen during electrolysis of
the second cathode tried. According to Notoya, the initial temperature
differential in this case corresponded to a 100% power excess.
Subsequently, a persistent excess of about 4 Deg. C was observed, which
she said corresponded to a 30% power excess (the reduction in fractional
excess was attributed by Notoya to contamination).
The persistent excess power which Notoya obtained at MIT was about 0.75
Watts, and the cathode volume was about 0.05 cm{3}, leading to a volume
averaged excess of 15 Watts/cm{3}. At Nagoya, the cell ran at a 4 Watt
excess, corresponding to 80 Watts/cm{3}. She claims that she has observed
a maximum of 200 Watts/cm{3} excess. A few hours of operation at 15
Watts/cm{3} is sufficient to defeat a chemical explanation, which was done
at MIT. The power excess demonstrated at Nagoya would defeat a chemical
explanation in tens of minutes, and the cell ran for many hours.
Little is known about loading ratios (H/Ni) while heat is produced; no
information is available about potassium loading in the Ni; there is
apparently an alkaline intermetallic layer formed which is at least
several hundred Angstroms thick which may play a role. Nothing is known
about the temperature sensitivity of the effect; Notoya observes the
excess power to be essentially linear in applied current down to her
lowest values (50-100 mA, and about 1 cm{2} geometric area at MIT; the
high current levels approach 1 amp).
Notoya obtains her best results with cathodes which have an extremely
high area ratio (real area to geometric area), and she uses cathodes with
an area ratio of several thousand (and a reduced density of about 6
gm/cm{3}). The effect is apparently extremely sensitive to contamination,
especially to oils. She observes an increase of 20% in calcium
concentration (near 20 ppm) in the electrolyte, which she believes may be
anomalous.
I do not think that there is yet any particular contradiction between the
light water experiments of the Mills type and the light water blanks in
Pons-Fleischmann experiments. The light water blanks in Pd/H experiments
run in a H[2]O/LiOH electrolyte give zero excess power in most everyone's
blank experiments these days; the Mills experiment uses a Ni cathode with
a H[2]O/K[2]CO[3] electrolyte. These are really very different systems. In
any event, in time any connections between the two systems will be
clarified.
Based on Notoya's work, the evidence in support of a light water effect
has improved significantly. The effect which she observes is so great
that there appears to be no simple explanation for it.
So is there a light water heat effect? At this point, I am not yet sure
one way or another. On the plus side: (1) the effect is large, (2) looks
to be nuclear given the excess heat numbers, and (3) can be reproduced.
On the minus side (from my point of view): (1) the effect has been
studied by a relatively small number of groups for a relatively short
time, (2) the effect appears to be somewhat insensitive to choice of
electrolyte (claims{41} of heat production have been made for experiments
which have used other alkali-carbonates such as Li[2]CO[3], Na[2]CO[3] and
Rb[2]CO[3]) and to some degree the choice of cathode (positive results
were reported{47} for Ni, Ag, Au and Sn electrodes). The reason which I am
uncomfortable with the insensitivity of the effect to cathode and
electrolyte comes from potential difficulties associated with finding a
reaction mechanism that would show such an insensitivity.
The experimentalists have grown used to the idea that deuterium gives
anomalies and hydrogen does not; the theorists who believe in fusion
mechanisms are comfortable with positive effects in deuterium and
negative effects in hydrogen. A light water heat effect causes
consternation in both camps; it would be exceedingly difficult to
reconcile with a fusion mechanism.
The neutron transfer model which I have been looking at (described
briefly below) needs a neutron donor (usually deuterium) and an acceptor
nucleus, and therefore has somewhat fewer constraints; nevertheless, I do
not relish the prospect of attempting to explain an apparently general
light water heat effect where the nuclei present are widely different
from one cell to another. An experimental determination (and
confirmation) of the ashes in any of these experiments would of course
greatly improve the situation.
As a result, I am not yet sure that there is a light water effect. I will
be surer one way or another when more confirmations (or
non-confirmations) are reported. I will be surer when Notoya, who has
worked on her experiments only since last August, has had more time to
think about her experiments and to improve them. I will also be surer in
time after the cold fusion community has had more time to study and to
evaluate the experiment.
13. The successful production of significant excess energy must give rise to
ashes of one sort or another. It is not currently known what reactions
are occurring; consequently, it is not obvious what ashes are to be
expected. Energy excesses in the range of 1 MJ to 10 MJ have been
reported in several experiments; we will consider briefly the
implications of excess power generation, both per joule and for a 10 MJ
total excess.
Conventional *dd*-fusion reactions producing 10 MJ would yield more than
10{19} neutrons, and a roughly equal number of tritium atoms. Pons and
Fleischmann's recent measurements{48} of the neutrons produced from their
cells yield 5-50 neutrons per joule, low by more than 10 orders of
magnitude from what would be predicted for conventional *dd*-fusion.
Tritium is not produced in their experiments, with a limit which is
probably on the order of 10{4} tritium atoms per joule; low by at least 8
orders of magnitude.
It has been suggested that the {4}He branch of the *dd*-fusion reaction is
somehow favored, and several searches for {4}He have been made. The
conventional {4}He branch yields a 24 MeV gamma, which is not observed
when heat is produced. The reaction energy would have to go elsewhere to
be qualitatively consistent, and many in the field believe that energy
transfer to the lattice occurs. Many measurements have been performed
seeking {4}He in the cathode after the experiment; my impression is that
it is simply not there quantitatively by many orders of magnitude.
There have been some efforts seeking {4}He in the gas stream produced
during electrolysis; Miles focused the attention of the community on this
issue last year at Como when he claimed the observation of {4}He which at
its highest levels might account for roughly 10% of the excess energy.
Scaramuzzi and De Ninno{11,12} described a new cell, calorimeter plus
helium detector with which they plan to attempt a confirmation; other
groups are acquiring mass detection capability for similar studies. The
measurements of Yamaguchi{22,23} described above has also raised interest
in helium detection.
I would think that by next year's conference, that there will be a
consensus by many groups established on whether substantial helium is
produced or not.
If the pragmatic point of view is adopted that whatever reaction is
occurring is not constrained by theoretical preconceptions, then the
search for the ashes is generalized considerably to include possible
isotopic shifts or anomalies, and the possible production of elements or
isotopes not initially present.
A large number of studies have been reported at the international
conferences in which the cathode surface has been analyzed for the
presence of trace elements. Due to the nature of electrochemical
deposition in real systems, quite a long list of surface contaminants are
found at significant levels, hopelessly complicating any straightforward
*ab initio* experimental search.
The number of nuclei which is sought is on the order of 10{12} per joule
(or 10{19} per MJ), which either helps or hurts depending on the point of
view. Present in large quantities are D, O, Pd, Li, and H. Determining a
relative isotope shift between deuterium and hydrogen is generally deemed
not to be feasible, given the presence of hydrogen as a ubiquitous
universal contaminant. Isotope shifts in oxygen are not currently
predicted by anyone in the field, and have never been studied in
Pons-Fleischmann experiments to my knowledge.
The first serious claim of possible isotope shifts in heavy elements with
which I am familiar was made by Rollison at the NSF/EPRI workshop in 1989
(Rollison subsequently had to back down from her claim -- see the
proceedings of the Salt Lake City conference). The glow discharge
observations described by Kucherov{13-16} and the Chinese group{17-20} imply
isotope shifts in Pd and other metals.
The production of 10 MJ of energy in a Pd cathode (containing 0.1 mole of
Pd) would give rise to modifications of the Pd isotope distributions
(assuming Pd were fuel) at the 0.0002 level, assuming arbitrarily 5 MeV
per reaction. The prospect of proving this experimentally if it is in the
bulk is judged to be impractical. If the reactions occur near the
surface, then the numbers improve; the "noise" associated with natural
isotopic separation also increases. Searches for such surface isotope
shifts have been reported, and continue to be performed; such searches
for now remain in the background of the field.
Lithium appears to be required for heat production in Pons-Fleischmann
experiments, although it is unknown whether it plays any nuclear role.
Thompson, formerly of Johnson-Matthey, reported{49} that the lithium on
the surface of a Pons-Fleischmann cathode that had been involved in
heat-producing experiments showed a depletion of {6}Li relative to the
natural abundance (down to about 4%). Pons and Fleischmann had reported
(in the Salt Lake proceedings) that the lithium which they had used was
initially enriched in {6}Li (11%); Thompson noted this in his talk,
quoting an initial concentration of 9-11%, but said the Johnson-Matthey
group did not have a before to compare with their after.
During the questions following Thompson's talk, McKubre noted that the
Johnson-Matthey analysis only looked at the surface, and that any lithium
present in the bulk might provide an internal reference. Thompson said
that he thought that this suggestion could be tested. The conference
proceedings from Johnson-Matthey states that no lithium is detected in
the bulk,{50} which would imply that it will not be possible to establish
an internal reference retrospectively.
The amount of lithium present in a cathode is an interesting question.
Gozzi reported last year the results of studies to determine Li loading
in Pd during electrolysis, and found the very high number of 5% by
monitoring the Li lost from the electrolyte. I questioned him at the
conference (he presented{50} some nice positive results from his torus of
cells where he monitors for heat, neutrons, tritium, helium, and I think
gammas; unfortunately, I am lacking sufficient documentation of his
results to present more details in this review), since several papers
presented at each of the international conferences showed per cent level
surface concentrations which fall rapidly on the micron scale into the
bulk of the cathode (an exception to this was the measurements presented
by Nakada{51} et al showing lithium profiles with significant lithium in
20-30 microns). Lithium concentrations were measured by Myamoto et
al,{52,53} who obtain Li/Pd ratios between 3 X 10{-4} and 3 X 10{-3}. I
suspect that the Li/Pd ratio is probably sensitive to cathode properties,
to the electrochemistry and loading time; one possible explanation of the
long loading time required for Pons-Fleischmann cells, and remarked on
explicitly by McKubre,{2} was that extra time beyond the deuterium loading
time required to see the heat effect might be due to a necessity to
achieve significant loading of another species, such as lithium or other
light interstitials.
I note here that energy production at the level of 100 MJ/mol would yield
an observable (2%) isotope shift in lithium if the lithium concentration
were at the 1% level, and if the bulk lithium did not substitute with
lithium in the electrolyte. The numbers are worse if the electrolyte
lithium is included, but not so bad to prohibit a measurement.
Unfortunately, very few groups are currently pursuing the lithium isotope
shift problem; I consider it to be an important question, especially in
light of the initial Johnson-Matthey positive measurement.
14. B. Stella{54} presented a poster that I passed by twice; the title talks
about the "stimulated emission of neutrons," that is of course impossible
-- neutrons are fermions, and can of course not participate in stimulated
emission. The third time by, Stella grabbed me and walked me through his
poster (for which I am thankful, otherwise I would have missed it).
In essence what the experiment consists of is taking a Pons-Fleischmann
cell, putting it inside a 40 % efficient neutron detector underground in
the Gran Sasso INFN laboratory, and directing an incident neutron beam
(of about 30 neutrons/sec) with a substantial thermal component at the
cell. Fast (2.45 MeV) neutrons are measured originating from the cell,
and a gain of about 2 fast neutrons for every incident neutron is
claimed.
After talking to him, I was given to understand that for 30 neutrons/sec
input that 60 or more neutrons/sec were measured (taking into account the
neutron detector efficiency). I asked if the ratio held up at a higher
input flux, and he said that they had done experiments up at 500/sec
incident, with the same basic neutron gain (but that their neutron
detector suffered from saturation problems at such a high flux).
I asked whether the effect was reproducible. Stella said that they had
done two runs (each run takes about a week to do) so far, and that they
hoped to be able to do some more in the near future.
I note that a neutron gain of 2 would be a very important result, if
true, with rather important implications. I note also that this report of
two observations (with a modest signal relative to noise) is the first in
which such an effect has been claimed, and that no reproductions from
either this group or any other group has been made.
NEGATIVE RESULTS
1. A famous hydrogen-in-metals physicist, Y. Fukai, gave a presentation of
the basic problems facing theorists attempting to provide an explanation
of the anomalies.{55,56} I thought that this talk was excellent, and Fukai
is really very knowledgeable; it is clear that the basic physics issues
(the Coulomb barrier, screening, and solid state issues) that he
discussed must be addressed theoretically, especially in the case of
theories based on fusion reaction mechanisms.
Fukai also presented a negative result{57} involving a search for neutrons
that might be induced as a result of the generation of fractures in metal
deuterides. The highest result observed was for fractured TiD, 1.8 q 0.1
cpm, versus a background of 1.27 q 0.05 cpm.
I was impressed that he attended, since I am convinced that mainline
scientists of his caliber will play an increasingly important role in the
field. After talking to him, it became clear that some scientists present
who were not in the field had received very strong encouragement to
participate.
His talk was not well received by a number of those in the field, and he
was criticized during and after his presentation.
2. There was a negative result on a measurement of neutrons from a
Pons-Fleischmann cell originating out of the physics department at Osaka
University,{58} the poster of which looked very interesting. The group had
a high-resolution Ge detector looking at gammas produced inelastically by
neutrons impinging on an Fe plate placed between the detector and a Pd
heavy water electrolysis cell. With this system, the group was able to
place an upper limit of 1.6 X 10{-24} fusions/dd-pair.
There was another negative result on the fusion rate as determined by the
relative absence of 3 MeV protons reported by a group from Tokyo
Metropolitan University.{59} I did not see this poster. According to the
abstract, the upper limit on the fusion rate from this measurement was
1.3 X 10{-24} fusions/dd-pair.
3. D. Morrison of CERN presented a paper{60} that criticized the experiments
in the field, and used data from an analysis of the literature published
in the field to show that interest in the field is declining, symptomatic
of "pathological science".
Morrison made a number of arguments, most of which are restated and
amplified in his recent review{61} of the Nagoya conference (his Cold
Fusion Update No. 7 on the computer network; my copy is dated 12-17-92).
I will attempt here to summarize briefly what I think are key points
(drawing from his conclusions listed in Update No. 7), and to provide
some commentary on the points.
The major point of Morrison's presentation involves the inconsistency
between the claimed excess heat production, which would correspond to on
the order of 10{12} reactions per second, and the low tritium and neutron
signals which are lower by many orders of magnitude. For example,
Morrison uses the upper limit on neutron emission in the Kamiokande
experiments (10{-4} neutrons/sec) to place an upper limit on heat
production which is lower by 16 orders of magnitude. Morrison also noted
that the mean distance between deuterons in the lattice is larger than
for D[2], which implies that fusion reaction rates in a lattice would be
expected to be smaller than the very low numbers which are well-known for
D[2].
A weakness of the limiting argument as stated by Morrison is the
presupposition that conventional *dd*-fusion is the operative reaction
mechanism; it has long been recognized by many (but not all) in the field
that the excess heat production can not be due to conventional
*dd*-fusion. I personally would accept Morrison's limit on the heat
production for the Kamiokande cells, specifically for the amount of
excess heat due to the conventional *dd*-fusion channel in those
experiments. Possibly more relevant for a limit on the *dd*-fusion
channel would be a neutron measurement in a heat-producing cell (there is
no report of any calorimetric excess heat production at Kamiokande), in
which case the limit claimed in other experiments is higher, but the
basic argument is unchanged. This issue has been discussed above.
Morrison advocates that due to the wide range of phenomena claimed (some
inconsistent with others), and since "poorly designed and artifact-prone"
experiments have been reported in the field, that only "good
fully-instrumented and fully-calibrated experiments that need few and
unimportant corrections" should be done; loading should always be
measured.
The claims of positive heat results in light water experiments appears to
be inconsistent with previous claims of heat production (in which the
effect was present in heavy water, and absent in light water). This issue
was commented on above.
Morrison points out that many negative results have been obtained which
contradict the claims of Pons and Fleischmann, and those of Jones.
Morrison points to the work of the GE group (R. H. Wilson et al, *J.
Electroanal. Chem.* 332, 1 (1992)), as well as a large number of other
experiments, in which no excess heat was observed in contrast to the
claims of Pons and Fleischmann. He points to the Kamiokande experiment as
the strongest refutation of the original claims of neutron emission by
Jones and coworkers.
This argument was presented by Morrison in a spirited fashion at the
conference. He made use of the statistics of papers published for and
against, seemingly as a route to help to decide whether an effect exists
or not. For example, of 727 refereed published papers in the compilation
of D. Britz, in each category of effect, there are more negative results
than positive results. Of experimental papers in this set, there appear
86 positive, 136 null, and 36 indecisive or contradictory.
Of the 8 experimental papers published in 1992 included in the Britz
compilation, 1 was positive, 6 nulls, 1 indecisive; of papers on proton
measurements, 1 positive, and 11 nulls; of papers on {3}He, 1 positive and
8 nulls; of papers on x-ray emission, 0 positives and 7 nulls. The subset
which Britz rates as being expert yields the results as: 1 positive, 19
null, 2 unclear and 6 technical; of those looking for artifacts: 1
positive, 14 null, 2 unclear, and 1 technical.
At issue in Morrison's discussion is whether there occur, or do not occur
anomalies (heat, particles, etc.) in deuterated metal systems. Taking a
vote by counting the number of published papers pro or con is certainly
one way of deciding the issue; most others at the conference who argued
for or against presented the results of an experiment or else the results
of a theoretical model.
Morrison went further at the conference; he used the results to support
his contention that interest in the field is dying out (experimental
papers: 72 in 1989, 128 in 1990, 48 in 1991 and 8 in 1992), which he said
was symptomatic of "pathological science". Although Morrison has written
about the field as an example of pathological science *Special Symposium
Proceedings on Cold Fusion* of the World Hydrogen Energy Conference, July
1990, p. 233), and he discussed pathological science at Nagoya, I did not
see an elaboration of his arguments in his review.
Whether the excess heat effect is real or not is a matter that either has
been, or else will be, settled by experiment; not by counting papers or
by discussing pathological science. Nevertheless, there is an issue
buried in Morrison's arguments which is of interest. The issue of
reproducibility is central in the field, especially given the early
history and associated problems. The dark clouds which currently hang
over the field today would likely not be present had the experiments been
easier to reproduce in 1989. While the degree of reproducibility of the
heat effect among groups working in the field has improved considerably
since 1989, it is true that not very many examples exist where an outside
effort has come back recently armed with the latest results and has
attempted a replication. This situation needs to be addressed in the
coming months and years.
4. J. Huizenga of the University of Rochester submitted a post deadline
abstract{62} that pointed out that there are two types of claims, one for
heat and one for low levels of neutrons. Huizenga maintains that there is
no evidence to support any relation between the two claims. The claims of
fusion products at a level down by twelve orders of magnitude from the
heat production do not support the notion that the heat is of nuclear
origin.
Although Huizenga was present, this paper was not presented.
THEORY PAPERS
All but four of the theory papers were presented as posters during two
sessions where I had posters to attend; consequently I was unable to spend
much time looking over the theory papers of others. I will nevertheless
attempt a summary of some of the approaches of the work based both on the
abstracts and on what I have seen of the approaches previously. Once again, I
warn the reader that my review of the theory papers in the field are biased by
my own point of view as to what physical mechanisms are responsible for the
effects being observed.
The theories may initially be divided up into two general categories;
those involving (modified) fusion mechanisms, and those not involving fusion
mechanisms. Papers considering fusion mechanisms face the two basic problems
of (1) arranging to get nuclei close enough together to fuse, and (2) possibly
modifying the fusion reaction profiles. We first consider papers describing
theories based on fusion mechanisms.
1. G. Preparata{63} has been working on theory for coherent *dd*-fusion
reactions; a major goal of the theory is to account for the heat
production by a modified *dd*-fusion reaction where the {4}He branch
dominates, and the gamma emission is replaced by energy transfer with the
lattice. He argues that a proper quantization of the low energy
electromagnetic field coupled to the metal electrons leads to enhanced
screening between deuterons. He then proposes that the {4}He branch is
favored by coherence factors that come about when the reaction energy (24
MeV) is transferred to the lattice.
In some sense, this is a version of the "classical" cold fusion model,
which would be essentially forced somehow to be true if Fleischmann's
initial conjecture that the effect was due to fusion were accepted. I
consider this general type of model to be essentially the only game in
town if it is assumed (following Fleischmann's initial conjecture) that
the reaction mechanism must be fusion. I spent 6 months working on it
myself in 1989.
However, none of this makes the fundamental problems associated with
screening and modification of reaction pathways any easier to solve.
2. There have been a number of speculative theories that have been based on
the notion that deuterons in a metal are well-described using Bloch-type
wavefunctions. In such case, the principal interaction of the deuteron is
assumed to be with the lattice, and deuteron-deuteron correlation effects
would be brought in at higher order. A computation of the *dd*-fusion
rate using uncorrelated orbitals yields anomalously high fusion rates, as
expected since it operationally leaves out the Gamow factor.
It has been suggested that the inclusion of the deuteron-deuteron
correlation terms might not lead to Gamow factors as low as in the
well-known case of molecular D[2]. S. Chubb and T. Chubb{64,65} have
recently turned to the problem of electron correlation in ground state
helium as an example where orbital and correlation effects compete, and
argue that the Hylleraas solutions show an unexpected degree of overlap
between the two electrons.
Multi-body fusion theories have been proposed,{66,67} that would ultimately
require deuteron-deuteron correlation to be essentially absent altogether
to operate. It is not clear how this could come about.
3. The possibility that anomalously large electron screening might occur is
the subject of a number of works presented at the conference.{68-71} The
basic idea is that if the coulomb repulsion between deuterons held in
neighboring sites was reduced, then the degree of overlap of the nuclei
would be increased, leading to a possibly measurable fusion rate. The
difficulty here is to arrange for an enormous enhancement (of some
unexpected sort) of screening in the metal beyond what screening occurs
in D[2].
4. Fast (multi-KeV) deuterons are able to overcome the coulomb barrier
sufficiently to fuse with a low but observable probability. There have
been suggestions that conventional mechanisms exist that could accelerate
enough deuterons fast enough to account for low levels of neutron
emission that have been reported. This explanation follows from the known
phenomenon in insulators that hundred eV ions are emitted from insulators
that undergo intense fractures; the corresponding effect is much weaker
in metals by several orders of magnitude.
Theories which propose anomalous ion acceleration in metal hydrides were
described in a number of abstracts.{72-75} A variant on this general
approach is discussed by Fukushima,{76} wherein recent observations of
conditions in sono-luminescence experiments are proposed to result in an
enhancement of the fusion rate.
5. Kim and coworkers examine screening effects and modifications of the
deuteron velocity distribution function that may occur at high
density.{77-79} This approach is applicable both to cold fusion and to hot
fusion problems; the authors believe that it may provide a solution to
the solar neutrino problem. The fusion rate may be higher or lower than
the conventionally calculated rate, depending on the condensed matter
environment. Kim believes that these effects may also help to account for
the anomalous branching ratio in cold fusion.
6. A low energy resonance in the D+D system would enhance the fusion rate at
low energy (no such resonance is known theoretically or experimentally).
An abstract was submitted describing a proposed novel "combined resonance
tunneling" effect,{80} that was not explained in the abstract.
7. The catalysis of fusion by a heavy negatively charged particle, extending
the essence of muon-catalyzed fusion, was made popular in 1989 by
Rafelski and others. An abstract on catalysis by an anti-diquark with
-4/3 charge was submitted.{81} From my perspective, this general approach
suffers from the absence of abundant known massive negatively charged
nuclear particles, and a reason why they should be appearing specifically
in Pons-Fleischmann type experiments.
8. V. A. Tsarev of the Lebedev Institute in Moscow described some
calculations suggesting that an increase in the tunneling probability
between deuterons would be expected due to lattice motion (my translation
of "violation of stationarity in lattice").{82} Rather than the
conventional kinetic or screening arguments often described, Tsarev
proposed that the lattice would provide a time-dependent potential that
would affect the deuteron wavefunction itself.
I cannot see how there would be any but the weakest of effects from such
terms; in time more documentation of this approach will hopefully be
available, and the essence of the proposal will become clearer.
Tsarev presented an interesting review of cold fusion research in Russia
and in neighboring countries formerly of the Soviet Union. I do not have
sufficient documentation (unfortunately) of his presentation to include a
section in this review. I note that the Russian work was reviewed last
year in an article by Tsarev and Worledge. {83}
A number of theorists, including myself, have gone away from fusion
reaction mechanisms. The motivation for this is to avoid the coulomb barrier
(if possible) and to find reactions with signatures that hopefully more
closely match the experimental observations. Each new non-fusion approach
carries with it specific problems and issues that are associated with the
specific reaction mechanism. Aside from this, any new approach must also
arrange itself to be consistent with physical law, observations in this and
other fields, and must presumably be functioning in a manner not previously
expected (lest it would have been found earlier). We describe such
contributions below.
1. Electron capture on a deuteron would lead to two virtual neutrons; if it
could be arranged for the virtual neutrons to be in proximity with
neighboring nuclei, then further reactions could occur. This approach was
described in two abstracts by J. Yang of the Dept. of Physics, Hunan
Normal University of China.{84,85} Yang proposes that the two neutrons form
a stable dineutron that reacts with deuterium to make tritium and a free
neutron, and with {105}Pd to make {106}Pd and a free neutron.
I consider this general approach to be one of the basic non-fusion
approaches that actually begins to try to address the coulomb barrier
problem. Once the electron capture occurs, the coulomb barrier is gone,
potentially leading to the possibility of something happening near room
temperature. One difficulty involved in this approach are that the
electron capture is mediated by the weak interaction, which really is
very weak, making it hard to obtain significant reaction rates. A second
difficulty is that virtual neutrons do not generally wander more than
fermis away from their point of origin, making it difficult for a virtual
neutron to reach another nucleus to interact.
2. Direct lattice-induced neutron ionization was described by Tani and
Kobayashi,{86} motivated by the broad neutron emission that has been
observed by several laboratories at energies higher than 2.45 MeV.
The possibility that sufficient energy may be transferred from the
lattice to a deuteron to disintegrate it is yet another significant
conceptual step away from working with fusion reaction mechanisms. If a
mechanism existed to do what Tani and Kobayashi proposes, the resulting
spectra would likely follow the photodisintegration cross section
generally qualitatively in shape, which would not be such a bad match to
Takahashi's data.
Once, I suspected that a single-step lattice-induced disintegration,
something like what is described in this abstract, might be possible; I
followed it up with a moderately sophisticated calculation (based on a
harmonic lattice, without including some of the effects described in the
abstract) that has been accepted for publication. The results of my
computation were that although it is possible in principle to transfer
sufficient energy to do the job, the energy transfer is sensitive to
sign; in the end, I concluded that single-step lattice-induced
disintegration could not be done (within the limits of my model), without
having individual nuclei with MeV-level kinetic energy in the lattice
initially to do the ionizing.
3. I submitted two abstracts on neutron transfer reaction mechanisms that I
have been exploring recently.{87-89} The basic reaction in this theory is a
two-step transfer reaction of a neutron from a donor nucleus (typically a
deuteron) to an acceptor nucleus located Angstroms to microns away. As
originally proposed, the lattice would contribute the energy to promote
the neutron from the donor, and take up energy at the acceptor;
calculations showed that this was not viable, and so a modified version
of the model in under development.
The revised model works similarly, except that the intermediate state is
virtual, as required since the lattice is unable to contribute energy to
ionize the neutron. When the neutron reaches the acceptor nucleus, then a
number of incoherent processes could occur, including gamma capture, and
capture to states that decay by alpha emission. There might be a
correlation between these decay products and the reaction products
observed by Kucherov. Alpha particles in this model would range up to 4.1
MeV (originating from neutron capture on {105}Pd).
Heat production might be accounted for if a long-lived metastable state
existed that was nearly resonant with the virtual neutron, and which
alpha decayed.
If the capture at the acceptor is preceded by energy transfer to the
lattice during the donor transfer (which has now been shown explicitly to
be allowed at least mathematically), or during scattering of the
intermediate state virtual neutron, then the coherent neutron capture
proceeds into long-lived ground state nuclei, which are born essentially
at rest. This mechanism could account for heat production (accepting onto
light interstitials such as {6}Li or {10}B) and anomalous slow tritium
production (accepting onto deuterium).
The primary difficulty with any reaction mechanism that involves a
virtual free particle is that such intermediate particles do not go very
far (typically fermis) from where they are born. I presented the results
of computations of the virtual neutron Green's function including lattice
effects,{88} and found that under conditions that phase coherence among
neighboring hydrogen isotopes is maintained in a periodic lattice, that a
usefully large and long-range contribution to the Green's function may
occur that would lead to observably large net reaction rates. Quantum
diffusion is conjectured to be able to set up the required coherence.
One weakness of the approach which has become apparent following the
conference is that the diffusion of hydrogen in metals generally proceeds
by a hopping mechanism, which would likely not establish phase coherence
of the sort required by the theory. In a loaded PdD lattice, some
population of the tetrahedral sites would be expected; this is of
interest since the tetrahedral to tetrahedral site barrier is expected to
be considerably lower than the octahedral to octahedral site barrier,
which might help the situation. The issue of coherence for such a
diffusion mechanism is under study.
WHAT WAS NOT PRESENTED
In spite of the relatively numerous set of papers that were presented at
ICCF3, there were several key players in the field who were not present or did
not give papers. I felt that the conference suffered from the absence of K.
Wolf, H. Menlove, E. Storms, E. Cecil, F. Will, S. Szpak, F. Lanza, and
several other key players in the field. Additionally, a paper from G. Chambers
(of NRL) that I had hoped to see was withdrawn by order of an associate
director of NRL.
Possibly controversial was the absence of a presentation by Ishida of
experiments at Kamiokande. During the past year and a half, a very large
number of measurements seeking neutrons from various cold fusion experiments
were carried out. Kamiokande is famous as one of the world's premier neutrino
detection facilities, and received considerable attention following the
observation of neutrinos from the 1987 supernova. A positive result of
observation of anomalous neutron emission at Kamiokande would be a very big
event, since Kamiokande is well-respected in the physics community.
Ishida's master thesis summarizes the results of over 100 cold fusion
experiments that were done at Kamiokande. Although it is a fact that neutrons
were observed at low levels, there are questions about what is the origin of
the neutrons. In the thesis, Ishida proposes that the neutrons are due to
naturally occurring radioactive contaminants.
In the end, I think that the results from Kamiokande make either a weak
case in support of the existence of anomalous neutron emission, or else a
possibly disputable case in support of the non-existence of an effect. This
requires further explanation.
The emission of neutrons from Ti shavings in deuterium gas was reported
early on by Scaramuzzi from Frascati. Attempts to replicate the experiment met
with success at LANL, where both random and large bursts of neutrons have been
observed with high efficiency {3}He neutron detectors. Low level random
emission of neutrons is claimed, and bursts of up to several hundred neutrons
in a 100 mu sec period were observed. The reproducibility of these experiments
is not great, and in spite of the progress made at LANL in improving the
reproducibility of the effect, the success rate reported in the Como
proceedings was about 10%.
Menlove worked with the Japanese team to attempt a confirmation of the
LANL results. Due to the constraints imposed by the nature of the facility,
the number of runs which were attempted on Menlove's samples were 6. According
to Menlove, one of these samples might have shown something. If a case were
then to be made that the Kamiokande results disprove the Menlove's
observations at LANL, this argument is at best weak, since the probability of
obtaining a null result is on the order of (0.9){6} = 0.53 for these
experiments.
Some have made the case that since no very large bursts (~100 neutrons)
were observed in any of the more than 100 experiments (which would improve the
statistics), that this refutes Menlove's positive observations of large burst
obtained at LANL and reported at Como. Lacking from this argument is an
estimate of expected frequency of bursts from the various experiments that
were done. If the expected rate of large neutron bursts were negligible in the
Portland cement experiments, for example, then doing many of them should not
alter a conclusion regarding a Menlove experiment.
The poor reproducibility of the effect, in addition to the difficulty of
determining in a post-analysis what is the difference between a cell that gave
a signal and one that did not, prompted Scaramuzzi to recommend at Como that
this line of investigation should make way for other approaches which are less
frustrating. Research on Frascati cells has largely ceased in the field.
The Kamiokande experiments were discussed in the talk by S. Jones,{90} who
was a collaborator in the experiments at Kamiokande. Jones argued that the
conjectures made by Ishida about radioactive contaminants had been
subsequently tested by introducing the proposed contaminants and measuring the
resulting signals elsewhere; the resulting neutron emissions did not agree
with the Kamiokande results. Jones therefore described the results as
supporting the presence of anomalous neutron emission.
I do not think that we have heard the last of this discussion. I would
hope that in the future Kamiokande would try again, perhaps with experiments
which have larger signals and higher success rates. For example, the
experiment described by Kucherov would yield signals up to eight or nine
orders of magnitude above background at Kamiokande if there were any way to
field it there.
Also absent from the conference were prominent US skeptics who have in
one way or another have made technical contributions to the field in the past.
The absence of such individuals indicates the lack of any significant respect
that the cold fusion field currently has among the scientific community. I
would have been interested in the response of such skeptics following many of
the papers presented at the conference; but alas, it was not to be. At the
conference, little in the way of substantive technical criticism of the best
heavy water calorimetry results was offered by any of the participants. If
there exist skeptics who are familiar with the Pons and Fleischmann
calorimetry or the SRI work and believe that they know what might be
technically in error, your technical input would be greatly appreciated.
CONCLUSIONS AND DISCUSSION
Was the conference sufficiently strong technically to turn the tide, to
settle the seemingly endless controversy as to whether there is or is not any
new anomalous effect? I thought that it was. I regard the technical issue of
whether there is a reproducible anomalous excess power effect in heavy water
Pons-Fleischmann experiments to have been settled at this point; I think that
there is clearly an effect.
For such a significant conference, it has been largely ignored by the
scientific community. Wrongly so, I think. The majority of scientists are
currently ill-informed of the experiments, the implications, the arguments, or
the goals of ongoing research in the field. At some point this needs to
change, but I confess that I do not see how it might happen in the foreseeable
future.
The name "cold fusion" has been adopted by the field to some degree by
default. This name implies a generic physical reaction mechanism (fusion), and
because the experiments involve deuterium, the name further presupposes
specific reactions (*dd*-fusion reactions). But *dd*-fusion is expected to
produce neutrons and tritons, neither of which are quantitatively present with
the excess heat. Scientists who are not in the field are discouraged because
the expected fusion products are not present in quantities commensurate with
the observed energy production, and scientists working in the field have not
come up with an explanation in three and a half years as to why deuterons
should fuse that is acceptable to the scientific community.
There have been proposals to change the name of the field: "solid state
nuclear physics" has been suggested; "nuclear effects in metals" has also been
put forth. I would strongly endorse a name change.
A reviewer of this manuscript has pointed out that even these names
presuppose a nuclear component to the effect, which in the reviewer's eyes
remains to be demonstrated, and has recommended "hydrogen energy" or "hydrogen
in metals", with the understanding that "hydrogen" is to include the isotopes.
The field continues to receive considerable bad press, which at this
point is not warranted. For example, I have recently obtained a copy of a
review of the Nagoya conference by D. O. Morrison, which has received very
wide distribution; it is unfortunate that the only updates about the field
received by most of the physics community is through such a biased channel.
This simply must change. I am open to suggestions as to how this situation
could best be changed.
There are precious few sources of potential funding in this area,
especially in the US. I am convinced that DOE should be funding a significant
effort in the US, the goal of which should be to find out what is going on, so
that an informed and rational judgement can be made about any potential of the
effect to meet US and world energy requirements. One basic claim that has been
made is that excess energy at a level which must be nuclear (but is certainly
not conventional *dd*-fusion) is observed in the Pons-Fleischmann experiment
and variants; this is something that the DOE should be interested in.
So what is it that should be done? The list is very long, but I will
attempt to enumerate some of what I think are a few relevant goals:
1. Verification of a heat effect: I am convinced that the Pons-Fleischmann
cells can produce excess energy of a nuclear origin based on the amount
of energy per atom evolved. The scientific community does not accept
this. This issue really needs to be put to rest, and the associated
controversy ended.
Pons and Fleischmann have been publishing further details of their own
work in refereed journals and in readily available conference
proceedings, and more papers are currently in the pipeline. Details of
the work of many other groups is also readily available.
Considerably more is known about the Pons-Fleischmann cells than in 1989,
and the reproducibility of the effect has been improved considerably. SRI
has produced documentation of criterion which, if met, carries the
guarantee that similar experiments at SRI have produced heat reproducibly
with a very high success rate. Palladium cathodes from sources other than
Matthey-Johnson have now shown the effect.
Significant deficiencies have been identified in the principal negative
experiments which were done in 1989; the main criticisms of these
experiments was that a high loading was not achieved and held. For
example, the method developed at SRI requires very high loading (D/Pd
ratio near 0.90) to be maintained for about a week. Since positive
results have been obtained at lower loadings, this constraint is likely
not to be absolute; nevertheless, many in the field believe that quite
high loadings do improve the reproducibility of the effect.
I do not know how this controversy is to be ended, but I know that it
does need to be ended in a satisfactory manner. The basic experiments
have been done, they have been repeated in many different ways by
numerous groups, and the effect is observed with considerably better
signal to noise ratio than in 1989.
Scientists in the field have gone to extremes in attempts to satisfy
skeptics. Cells were stirred, blanks were done, extremely elaborate
closed cell calorimeters have been developed (in which the effect has
been demonstrated), the signal to noise ratio has been improved so that
positive results can now be claimed at the 50 sigma level, the
reproducibility issue has been laid to rest; but still it is not enough.
I have heard some skeptics saying that a commercial product is the next
hurdle to be jumped through before any significant funding can be
justified. This is simply not right.
2. Basic reaction mechanisms for heat production: To date the claims of the
observation of heat anomalies in metal deuterides have not been
accompanied by any clear positive evidence for reaction mechanisms.
Anomalous heat generation would have to have a fuel, and would have to
have ashes; the confirmed identification of either fuel or ashes would
help tremendously towards a determination of a reaction mechanism.
I think that progress in this field is hindered by the absence of even a
rudimentary understanding of the basic reaction mechanisms involved
(there are of course theories, but to date there is no positive
experimental confirmation of any proposed theory). At some point, the
principal experimentalists in the field simply must take this issue
seriously. Having an understanding of what the reaction mechanisms are
would provide numerous benefits: (1) guidance as to what experimental
parameters are expected to be important for optimizing reaction rates;
(2) improvement of the general quality of the science being done in the
field, especially as perceived by those not in the field; (3) allows
those working in the field to focus more clearly on the issues that are
most important. From the point of view of funders or potential funders, a
knowledge of how the effect works allows the possibility of assessing
more accurately potential future applications.
The determination of fuel and ashes requires high sustained
volume-averaged heat production. In the case of {4}He production, an assay
of the gas stream is required; in the case of assays for other elements
and isotopes, careful mass spectroscopy (and the presence of a small
electrolyte volume) will likely prove to be most important.
3. Verification and reaction mechanisms for other anomalies: Quite a few
anomalies have by now been associated with deuterium in metals
experiments, including observations of neutrons, gammas, fast ions,
tritium, and helium production.
None of these effects are currently accepted by the scientific community;
as in the case of the heat effect, some way is needed to arrange for a
consensus as to which of the effects are real. It would seem to me that
the most dramatic claims come from the glow discharge experiments; most
significant would be if these experiments could be further reproduced and
verified.
I think that experiments which produce energetic (MeV-level) nuclear
products provide essential information relevant to the issue of reaction
mechanisms. For example, a confirmation of significant isotope shifts and
strong gamma emission from heavy elements would place very strong
constraints on proposed reaction mechanisms. A detailed study of
precisely which gamma lines are produced would likely shed light on how
the gamma lines are excited, which provides further input on reaction
mechanisms.
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